Showing posts with label chemical. Show all posts
Showing posts with label chemical. Show all posts

Wednesday, July 22, 2015

Invention of cellulose acetate

The acetate of cellulose was first prepared in 1869 by the French chemist Paul Schutzenberger by reaction of cellulose with acetic anhydride.

The reaction was not easy to carry out, and it was not until 1894 that it was found that the reaction could be greatly facilitated by the use of sulfuric acid as catalyst. The product was the triacetate, in which each of three hydroxyl groups of the glucose rings of cellulose are acetylated.

In 1904 George W. Miles, an American chemist invented cellulose acetate as a safer alternative to celluloid. Cellulose acetate finds use as a synthetic fiber but has very steep competition from other polymeric fibers epically polypropylene and polyester fibers.
Camille Dreyfus
In 1905 Swiss chemist Dr. Henry Dreyfus furthered this work and created cellulose acetate, less flammable thermoplastic than Hyatt’s celluloid, and produced a ‘dope’ of cellulose acetate dissolved in acetone. The primary use of this dope at the time was for the wings of fighter aircraft used in the 1914-1918 war.

Henry later launched a business with his brother, chemist and industrialist Camille Dreyfus.

Used in injection molding, the material they made took shape as food packaging, refrigerator dishes and trays, egg cups and place mats.
Invention of cellulose acetate

Monday, April 7, 2014

The invention of chemical battery by Alessandro Volta

In Baghdad, archeologists discovered what they think was an electric cell made in ancient Babylon in about 500 BC. The cell consisted of a clay rod inside a copper cylinder.

The real history of modern battery development began in the 1790s, when Italian scientist Professor of Natural Philosophy (physic) at the University of Pavia, Alessandro Volta made the first modern electric cell. 

Volta’s famous experiment, described in a letter to the Royal Society of London in 1800, consisted of a disc of zinc and a disc of silver separated by cloth soaked in salt solution.

Volta placed many cells on top each other to make a battery. A continuous current of electricity was produced as soon as the two (silver disc and zinc disc) were connected by a wire conductor.

Volta became famous because of this invention and the words ‘volt’ and ‘voltage’ are named in honor of him.

Known as a ‘pile’, Volta presented his new invention – the Voltaic Cell to Napoleon Bonaparte in 1801, and became the father of the world first ‘dry’ battery.

Volta theory, that the joining of the metals themselves created the current, was not quite accurate. Several years later Michael Faraday and others proved that the current resulted from the chemical action of the salt solution on the metals.

The next step in the development of batteries was the invention of the Daniel cell by John Daniell, Professor of Chemistry at King’s College, London.
The invention of chemical battery by Alessandro Volta

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